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- W2000358734 abstract "Trithiocarbonate group was introduced into the polystyrene-b-poly(ethylene oxide) (PS-b-PEO) block copolymers as the junction of the blocks through RAFT polymerization. Mixed PS and PEO brushes with a V-shape were prepared by anchoring the trithiocarbonate group on the planar gold substrate. The morphology of the V-shaped brushes was characterized by atomic force microscopy (AFM) and the surface composition responsive to solvent treatment was detected by X-ray photoelectron spectroscopy (XPS). Different morphologies were observed for the V-shaped PS-b-PEO brushes, depending on the chain structure and solvent treatment. The highly selective solvent for PEO, ethanol, can intensify or induce microphase separation of the V-shaped brushes, leading to vertical microphase separation. When the V-shaped brushes are treated with the co-solvent, THF, miscible morphology, lateral microphase separation, and vertical microphase separation are observed as the PS block length increases. After treatment with the non-selective poor solvent, cyclohexane, the V-shaped PS106-b-PEO113 brush, exhibits a laterally microphase-separated morphology, but the V-shaped PS52-b-PEO113 and PS253-b-PEO113 brushes are vertically microphase-separated." @default.
- W2000358734 created "2016-06-24" @default.
- W2000358734 creator A5055298981 @default.
- W2000358734 creator A5069657194 @default.
- W2000358734 creator A5071999954 @default.
- W2000358734 creator A5085336450 @default.
- W2000358734 date "2012-10-01" @default.
- W2000358734 modified "2023-10-14" @default.
- W2000358734 title "Preparation and characterization of V-shaped PS-b-PEO brushes anchored on planar gold substrate through the trithiocarbonate junction group" @default.
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- W2000358734 doi "https://doi.org/10.1016/j.jcis.2012.06.067" @default.
- W2000358734 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22832097" @default.
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