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- W2000359969 abstract "The polymerization of 2-methylpropene initiated by the mixture Lewis acid-2-azido-2,4,4-trimethylpentane was studied in various conditions. It was shown that BF3 gave an appreciable polymerization yield, while diethylaluminium chloride gave only low yields. The functionalization of poly(2-methylpropene) by an azide group was observed, and a functionality of 0.6 was obtained. This is the first example of the functionalization of polyalkene through direct cationic polymerization of the monomer by coinitiation giving macromolecules terminated by a function containing a carbon-to-nitrogen bond. However, elimination reaction is probably responsible for the partial functionalization of the oligomers." @default.
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- W2000359969 date "1993-11-01" @default.
- W2000359969 modified "2023-10-14" @default.
- W2000359969 title "Synthesis of polymers containing pseudohalide groups by cationic polymerization—6. Azidotelechelic poly(2-methylpropene) by polymerization initiated by the system Lewis acid-2-azido-2,4,4-trimethylpentane" @default.
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- W2000359969 doi "https://doi.org/10.1016/0014-3057(93)90053-i" @default.
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