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- W2000361474 abstract "A non-aldol aldol-cuprate opening generates the polypropionate 11 from the epoxy ether 14 in eight steps as a single diastereomer. A highly stereoselective aldol reaction of 8 with 9 gives the aldol product 7 in high yield and excellent diastereoselectivity, due to double stereodifferentiation. This compound was used for an efficient synthesis of the natural product auripyrone B 2 in only 20 steps and 8% overall yield from 14 using a late-stage spiroketalization onto a stable hemiketal as the final key step." @default.
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- W2000361474 date "2010-05-25" @default.
- W2000361474 modified "2023-09-28" @default.
- W2000361474 title "Total Synthesis of Auripyrone B Using a Non-Aldol Aldol−Cuprate Opening Process" @default.
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- W2000361474 doi "https://doi.org/10.1021/ol100985n" @default.
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