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- W2000366834 abstract "The temperature dependence of the formation of negative ions from chloroethylenes (cis-1,2-C2H2Cl2, trans-1,2-C2H2Cl2, C2HCl3, C2Cl3F, C2Cl4) and bromoethylenes (cis-1,2-C2H2Br2, trans-1,2-C2H2Br2, C2HBr3, 1,1-C2Br2F2) was studied using negative chemical ionization mass spectrometry. The halide ion was observed for all samples. Other fragment anions, (M-X)- (parent molecule, M, less one halogen atom, X)- and X2- were produced for some samples. The former was observed for trans-1,2-C2H2X2 and C2HBr3, and the latter for 1,2-C2H2Cl2, cis-1,2-C2H2Br2, and C2HBr3. The branching ratio of X2- and (M-X)- decreases with increasing the temperature. The branching ratio of X2- is considerably different for chloroethylenes and for bromoethylenes." @default.
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- W2000366834 date "2000-07-01" @default.
- W2000366834 modified "2023-09-26" @default.
- W2000366834 title "Negative Chemical Ionization Mass Spectrometric Studies on Dissociative Electron Attachment Processes of Chloroethylenes and Bromoethylenes" @default.
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- W2000366834 doi "https://doi.org/10.1246/bcsj.73.1491" @default.
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