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- W2000367757 abstract "The barrier to rotation around the N–N bond in 3,3′-biquinazoline-4,4′-dione is estimated to be 96 kJ mol−1, significantly higher than in acyclic tetraacyl hydrazines (84 kJ mol−1). Both dynamic chiroptical and NMR studies of 3,3′-biquinazoline-4,4′-diones which have an additional ring bridging the 2,2′ positions indicate that these compounds have a significantly higher barrier to rotation than the parent 3,3′-biquinazoline-4,4′-dione. Deracemisation of certain 3,3′-biquinazoline-4,4′-diones is possible via treatment with chiral acids at high temperature." @default.
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- W2000367757 date "2000-01-01" @default.
- W2000367757 modified "2023-10-18" @default.
- W2000367757 title "Tetraacyl hydrazines and 3,3′-biquinazoline-4,4′-diones; synthesis, studies of rotational barriers and deracemisation" @default.
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- W2000367757 doi "https://doi.org/10.1039/b004457l" @default.
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