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- W2000372647 abstract "[structure: see text] A family of chiral metallacyclophanes has been readily assembled based on robust Pt-acetylide linkage and characterized by a variety of spectroscopic techniques and X-ray crystallography. The steric congestion around the chiral dihydroxy groups in rigid metallacyclophane 4 prevents their reactions with Ti(O(i)()Pr)(4) to form active catalysts for enantioselective diethylzinc additions to aromatic aldehydes. In contrast, chiral dihydroxy groups in more flexible unclosed metallacyclophane 5 are effective ligands for enantioselective catalytic diethylzinc additions to aromatic aldehydes." @default.
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- W2000372647 date "2004-02-19" @default.
- W2000372647 modified "2023-10-10" @default.
- W2000372647 title "Chiral Metallacyclophanes: Self-Assembly, Characterization, and Application in Asymmetric Catalysis" @default.
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- W2000372647 doi "https://doi.org/10.1021/ol036111v" @default.
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