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- W2000374037 abstract "The use N-sulfonyl-protected hydroxylamines as bi-nucleophiles in iron-catalyzed propargylic substitutions allows the selective one-pot synthesis of four classes of substituted isoxazoles or isoxazolines from the same propargylic alcohols (21 examples) by simply tuning the nature of the base. By using an iron(III) catalyst and a base such as triethylamine (3 equiv), isoxazoles 3 are obtained in good isolated yields (56–95%), whereas N-sulfonyl-protected isoxazolines 6 are selectively obtained (77–93% yield) by using iron and gold catalysts in the presence of a catalytic amount of pyridine (10 mol%)." @default.
- W2000374037 created "2016-06-24" @default.
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- W2000374037 date "2010-09-14" @default.
- W2000374037 modified "2023-09-30" @default.
- W2000374037 title "A Versatile Iron-Catalyzed Protocol for the One-Pot Synthesis of Isoxazoles or Isoxazolines from the Same Propargylic Alcohols" @default.
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- W2000374037 doi "https://doi.org/10.1002/chem.201001461" @default.
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