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- W2000374222 abstract "Reaction of [(C4H9)4N]2Mo2O7 with hydrazones, R2CNNH2, yields the novel MoV/MoVI mixed valence octanuclear polyoxomolybdate, [(C4H9)4N]4[Mo8O24(OCH3)2]· CH3OH· H2O. The structure of the anionic cluster consists of a tetranuclear core [Mo4O8 (OR)2]4+ of edge-sharing Mo octahedra, coordinated to two bridging dipodal [MoO4]2− units and two corner sharing [MoO4]2− units. Crystal data: P21/n space group, with a = 17.166(2), b = 15.719(2), c = 18.933(3) Å, β = 95.08(1)°, V = 5088.9(8) Å3, Z = 2, Dcalc = 1.46 g cm−3. Structure solution and refinement based on 3626 reflections, R = 0.068." @default.
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- W2000374222 date "1989-01-01" @default.
- W2000374222 modified "2023-10-14" @default.
- W2000374222 title "Synthesis and structural characterization of a mixed valence octanuclear polyoxomolybdate, [(C4H9)4N]4[Mo8O24(OCH3)2] · CH3OH · H2O" @default.
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- W2000374222 doi "https://doi.org/10.1016/s0277-5387(00)80754-8" @default.
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