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- W2000378293 abstract "Mixed acetic sulphuric anhydrides obtained from both equimolar SO3–AcOH and SO3–Ac2O systems in liquid SO2 are found at low temperature (⩽–20°) in equilibrium between the keto (CH3·CO·OSO3Y) and enol (CH2:COH·OSO3Y) forms (Y = SO3– or Ac). At room temperature a cleavage reaction is shown to occur through the intermediacy of keten, which reacts further to yield oligomers and sulpho-derivatives [reaction (i)]. CH2:COH·OSO3Y [graphic omitted] CH2CO [graphic omitted] (i) This cleavage reaction appears specifically not to involve participation of acetylium ions, whereas previously these ions were normally considered as the principal precursor of keten intermediates." @default.
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- W2000378293 date "1980-01-01" @default.
- W2000378293 modified "2023-10-18" @default.
- W2000378293 title "Keto–enol equilibria in mixed acetic sulphuric anhydrides" @default.
- W2000378293 doi "https://doi.org/10.1039/p29800000662" @default.
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