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- W2000380361 abstract "We introduce a modified Becker-Döring system of equations which models the nucleation of two types of cluster from the same monomer. This competitive nucleation system is then studied in the coagulation-dominated asymptotic regime where a succession of timescales is identified through which the system passes, and in which the cluster distribution profile is described. The system is then subjected to a coarse-grain rescaling leading to a low-dimensional system of equations for macroscopically observable quantities. This system is also solved in the coagulation-dominated regime. Examples of the full system and the reduced system are solved numerically to show the similarities in the behaviour exhibited by their respective solutions. This study has applications to experiments involving crystallization where various morphologies of growing crystals are observed, and to protein crystallization, where gels and/or amorphous material precipitate out of solution simultaneously with crystals. We highlight how some aspects of observed phenomena may be determined by the kinetics of the process rather than by the relative thermodynamical stability of the two cluster types allowed within the system." @default.
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- W2000380361 date "1999-11-30" @default.
- W2000380361 modified "2023-10-16" @default.
- W2000380361 title "A Becker-Döring model of competitive nucleation" @default.
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- W2000380361 doi "https://doi.org/10.1088/0305-4470/32/49/315" @default.
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