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- W2000381002 abstract "In this work, we present a new synthesis and optical characterization of poly(styrene sulfonate) (PSS) films doped with neodymium ions (Nd). The optimization of the Nd-PSS films processing shows that the maximum Nd(III) incorporation is equal to 14%. The absorbance spectra in the UV–Vis-NIR region of Nd-PSS films present the typical transition bands of neodymium chloride (NdCl3) in aqueous solution. The infrared spectra display the PSS transitions with an enlargement in every band, as a result of Nd coordination. The UV–Vis luminescence of Nd-PSS films exhibits a spectral blue shift and a line shape definition as compared to PSS film, indicating a decrease in the interaction among the aromatic groups. In addition, the Nd-PSS emission at 1052 nm (9505 cm−1 – transition 4F3/2 → 4I11/2) was observed, independently of the neodymium concentration. Judd–Ofelt theory was used in order to obtain the Nd radiative transition rates." @default.
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- W2000381002 date "2006-08-01" @default.
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- W2000381002 title "Synthesis and optical characterization of poly(styrene sulfonate) films doped with Nd(III)" @default.
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- W2000381002 doi "https://doi.org/10.1016/j.chemphys.2006.03.014" @default.
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