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- W2000384877 abstract "Hexafluoro-t-butoxy radicals have been generated by reacting fluorine with hexafluoro-2-methyl isopropanol: Over the temperature range of 406–600 K the hexafluoro-t-butoxy radical decomposes exclusively by loss of a CF3 radical [reaction (-2)] rather than by loss of a CH3 radical [reaction (-1)]: (1) The limits of detectability of the product CF3COCF3, by gas-chromatographic analysis, place a lower limit on the ratio k−2/k-1 of ∼80. The implications of this finding in relation to the reverse radical addition reactions to the carbonyl group are briefly discussed. A thermochemical kinetic calculation reveals a discrepancy in the kinetics and thermodynamics of the decomposition and formation reactions of the related t-butoxy radical:" @default.
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- W2000384877 title "The kinetics of the gas phase decomposition reactions of the hexafluoro-t-butoxy radical" @default.
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- W2000384877 doi "https://doi.org/10.1002/kin.550150308" @default.
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