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• W2000385586 abstract "Five nitrophenylporphyrins were investigated as to their electrochemical properties in CH 2 Cl 2 containing 0.1 M TBAP. The investigated compounds are represented as ( NO 2 Ph ) x Ph 4-x PorM , where Por represents the dianion of the porphyrin macrocycle, Ph is a phenyl group on meso-position of the macrocycle, NO 2 Ph is a meso-substituted nitrophenyl group, M = 2 H , Pd II or Zn II and x = 1 or 2. Each porphyrin undergoes an initial one electron reduction at E 1/2 = -1.07 to -1.12 V where the added negative charge is almost totally localized on the meso-nitrophenyl group of the compound. This reversible reduction is then followed by one or more irreversible reductions of the nitrophenyl anion at more negative potentials which overlap with reduction of the conjugated porphyrin macrocycle. The initial one electron addition was monitored by thin-layer UV-vis spectroelectrochemistry which confirmed formation of a reduced nitrophenyl group in each case but also gave spectral evidence for a linkage of the one-electron reduction products in the case of the Zn derivatives, giving Zn porphyrin dimers or arrays which are characterized by a 14–15 nm red-shifted Soret band and two well-defined Q-bands, consistent with conversion from an unreduced four coordinate Zn II nitrophenylporphyrin to a five-coordinate Zn II complex with an unreduced porphyrin macrocycle." @default.
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• W2000385586 date "2014-08-01" @default.
• W2000385586 modified "2023-10-18" @default.
• W2000385586 title "Redox properties of nitrophenylporphyrins and electrosynthesis of nitrophenyl-linked <font>Zn</font> porphyrin dimers or arrays" @default.
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• W2000385586 doi "https://doi.org/10.1142/s1088424614500540" @default.
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