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- W2000386243 abstract "Perchloric acid solutions of Ru4(OH)48+ were prepared by the controlled-potential reduction of Ru(IV) at platinum electrodes in a high-speed coulometric cell. The solution spectrum of Ru4(OH)48+ is reported. Tetrameric Ru(III) ion decomposes in a reaction which is first-order with respect to its concentration, but independent of the acidity, to another species of the same valence state which is believed to be a dimeric ion (Ru2(OH)24+ or similar). Electrochemical reduction of this species yields Ru2+ which can be reoxidized only to Ru3+, the most stable of the Ru(III)-aquo ions." @default.
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- W2000386243 date "1983-01-01" @default.
- W2000386243 modified "2023-09-25" @default.
- W2000386243 title "Depolymerization kinetics of Ru4(OH)48+ and characterization of the reaction product: Dimeric Ru(III) ion" @default.
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- W2000386243 doi "https://doi.org/10.1016/s0277-5387(00)84343-0" @default.
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