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- W2000391475 abstract "Spectroscopic techniques to study the electron configuration and local coordination of a central atom by detecting inner-shell radiative decays following photoexcitation using hard X-rays are presented. The experimental setup requires an X-ray spectrometer based on perfect crystal Bragg optics. The possibilities arising from non-resonant and resonant X-ray emission spectroscopy are discussed when the instrumental energy broadenings of the primary (beamline) monochromator and the crystal spectrometer for X-ray emission detection are on the order of the core hole lifetimes of the intermediate and final electronic states. The small energy bandwidth in the emission detection yields line-sharpened absorption features. In transition metal compounds, electron–electron interactions as well as orbital splittings and fractional population can be revealed. Combination with EXAFS spectroscopy enables to extend the k-range beyond unwanted absorption edges in dilute samples that limit the EXAFS range in conventional absorption spectroscopy." @default.
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- W2000391475 date "2009-07-01" @default.
- W2000391475 modified "2023-09-29" @default.
- W2000391475 title "Hard X-ray photon-in photon-out spectroscopy" @default.
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- W2000391475 doi "https://doi.org/10.1016/j.cattod.2008.10.049" @default.
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