FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000393865> ?p ?o ?g. }

• W2000393865 abstract "Substituted tetraphenylporphyrinatozinc(II) complexes have been synthesized and characterized by various physicochemical techniques. The effects of substitution and counterions on the redox behaviour and EPR spectra have been examined. The EPR spectra revealed that chemical oxidation with bromine yields ZnT ( X - P ) P + Br - (species I) and a brominated tetraphenylporphyrin cation radical (species II). The former exhibits a labile electronic ground state (with 2 A 2 u ground state transforming into 2 A 1 u at 175 K), while the latter is characterized by a 2 A 1 u state. The lability in the electronic ground state for species I is discussed in terms of the change in molecular geometry as the temperature is lowered. The EPR spectra also revealed for the first time the formation of dimeric agglomerates of TPP cation radicals in low concentration below the electronic transition (i.e. near 170 K) wherein the paramagnetic sites are antiferromagnetically coupled." @default.
• W2000393865 created "2016-06-24" @default.
• W2000393865 creator A5028331487 @default.
• W2000393865 creator A5039074654 @default.
• W2000393865 date "2000-03-01" @default.
• W2000393865 modified "2023-09-27" @default.
• W2000393865 title "Effect of substitution on the redox behaviour and EPR spectra of zinc(II) substituted tetraphenylporphyrin cation radicals" @default.
• W2000393865 cites W137362595 @default.
• W2000393865 cites W165606226 @default.
• W2000393865 cites W1963747685 @default.
• W2000393865 cites W1967042608 @default.
• W2000393865 cites W1968469284 @default.
• W2000393865 cites W1984339168 @default.
• W2000393865 cites W1992413871 @default.
• W2000393865 cites W1996746539 @default.
• W2000393865 cites W2004982437 @default.
• W2000393865 cites W2011284839 @default.
• W2000393865 cites W2013808295 @default.
• W2000393865 cites W2017606649 @default.
• W2000393865 cites W2024208900 @default.
• W2000393865 cites W2028031650 @default.
• W2000393865 cites W2049326484 @default.
• W2000393865 cites W2055508803 @default.
• W2000393865 cites W2060526318 @default.
• W2000393865 cites W2062015981 @default.
• W2000393865 cites W2067031881 @default.
• W2000393865 cites W2082142902 @default.
• W2000393865 cites W2125250664 @default.
• W2000393865 cites W2337629445 @default.
• W2000393865 cites W2951639386 @default.
• W2000393865 cites W3139491730 @default.
• W2000393865 cites W3459286 @default.
• W2000393865 cites W4243835835 @default.
• W2000393865 doi "https://doi.org/10.1002/(sici)1099-1409(200003)4:2<192::aid-jpp193>3.0.co;2-5" @default.
• W2000393865 hasPublicationYear "2000" @default.
• W2000393865 type Work @default.
• W2000393865 sameAs 2000393865 @default.
• W2000393865 citedByCount "3" @default.
• W2000393865 crossrefType "journal-article" @default.
• W2000393865 hasAuthorship W2000393865A5028331487 @default.
• W2000393865 hasAuthorship W2000393865A5039074654 @default.
• W2000393865 hasConcept C121332964 @default.
• W2000393865 hasConcept C1276947 @default.
• W2000393865 hasConcept C139066938 @default.
• W2000393865 hasConcept C145148216 @default.
• W2000393865 hasConcept C149997192 @default.
• W2000393865 hasConcept C178790620 @default.
• W2000393865 hasConcept C179104552 @default.
• W2000393865 hasConcept C185592680 @default.
• W2000393865 hasConcept C187961010 @default.
• W2000393865 hasConcept C2778401137 @default.
• W2000393865 hasConcept C2778591166 @default.
• W2000393865 hasConcept C2779480358 @default.
• W2000393865 hasConcept C34814092 @default.
• W2000393865 hasConcept C46141821 @default.
• W2000393865 hasConcept C4839761 @default.
• W2000393865 hasConcept C544153396 @default.
• W2000393865 hasConcept C55904794 @default.
• W2000393865 hasConcept C62520636 @default.
• W2000393865 hasConcept C69523127 @default.
• W2000393865 hasConcept C75473681 @default.
• W2000393865 hasConcept C8010536 @default.
• W2000393865 hasConceptScore W2000393865C121332964 @default.
• W2000393865 hasConceptScore W2000393865C1276947 @default.
• W2000393865 hasConceptScore W2000393865C139066938 @default.
• W2000393865 hasConceptScore W2000393865C145148216 @default.
• W2000393865 hasConceptScore W2000393865C149997192 @default.
• W2000393865 hasConceptScore W2000393865C178790620 @default.
• W2000393865 hasConceptScore W2000393865C179104552 @default.
• W2000393865 hasConceptScore W2000393865C185592680 @default.
• W2000393865 hasConceptScore W2000393865C187961010 @default.
• W2000393865 hasConceptScore W2000393865C2778401137 @default.
• W2000393865 hasConceptScore W2000393865C2778591166 @default.
• W2000393865 hasConceptScore W2000393865C2779480358 @default.
• W2000393865 hasConceptScore W2000393865C34814092 @default.
• W2000393865 hasConceptScore W2000393865C46141821 @default.
• W2000393865 hasConceptScore W2000393865C4839761 @default.
• W2000393865 hasConceptScore W2000393865C544153396 @default.
• W2000393865 hasConceptScore W2000393865C55904794 @default.
• W2000393865 hasConceptScore W2000393865C62520636 @default.
• W2000393865 hasConceptScore W2000393865C69523127 @default.
• W2000393865 hasConceptScore W2000393865C75473681 @default.
• W2000393865 hasConceptScore W2000393865C8010536 @default.
• W2000393865 hasLocation W20003938651 @default.
• W2000393865 hasOpenAccess W2000393865 @default.
• W2000393865 hasPrimaryLocation W20003938651 @default.
• W2000393865 hasRelatedWork W1975130031 @default.
• W2000393865 hasRelatedWork W1975756090 @default.
• W2000393865 hasRelatedWork W1987581183 @default.
• W2000393865 hasRelatedWork W2002790189 @default.
• W2000393865 hasRelatedWork W2004601992 @default.
• W2000393865 hasRelatedWork W2006566435 @default.
• W2000393865 hasRelatedWork W2013841124 @default.
• W2000393865 hasRelatedWork W2014845928 @default.
• W2000393865 hasRelatedWork W2016775692 @default.
• W2000393865 hasRelatedWork W2023163539 @default.
• W2000393865 hasRelatedWork W2025678219 @default.
• W2000393865 hasRelatedWork W2065257662 @default.
• W2000393865 hasRelatedWork W2078569407 @default.
• W2000393865 hasRelatedWork W2550310631 @default.

• next