FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000394688> ?p ?o ?g. }

• W2000394688 endingPage "3302" @default.
• W2000394688 startingPage "3294" @default.
• W2000394688 abstract "Abstract Trimetallic oxoalkoxide complexes (Nb0.7Ta0.3)4O2(OMe)14(ReO4)2 (I), (Nb0.3Ta0.7)4O2(OMe)14(ReO4)2 (II) and (Nb0.5Ta0.5)4O2(OMe)14(ReO4)2 (III) were obtained by the interaction of rhenium heptoxide (VII) Re2O7 with niobium and tantalum alkoxides M2(OMe)10 (M=Nb, Ta) in toluene. The centrosymmetric molecules (I)–(III) can be considered as a product of condensation of two M2(OMe)9(OReO3) molecules with the formation of two oxo-bridges. The specific feature of the structure is the uneven distribution of metal atoms in the crystallographic positions, where one symmetry-independent position, connected via μ-O with a perrhenate ReO4− group, is predominantly occupied by niobium atoms, while the other one connected via alkoxide groups has a higher tantalum content. The distribution of Nb and Ta in the structure is truly even only for compound III. The niobium and tantalum content is varied to a different extent for I (less) and for II (more), which is apparently due to small differences in the sizes of these two cations, resulting in preferences for packing of different molecules in the structures. Thermal decomposition of (Nb1−xTax)4O2(OMe)14(ReO4)2 (x=0.3, 0.5, 0.7) in air leads to the formation of crystalline species of solid solutions based on tantalum and niobium oxides displaying semi-ordered pores with the size of 100−250 nm. In the dry nitrogen atmosphere, the decomposition leads to the amorphous complex oxides containing rhenium, niobium and tantalum." @default.
• W2000394688 created "2016-06-24" @default.
• W2000394688 creator A5036513853 @default.
• W2000394688 creator A5081897272 @default.
• W2000394688 creator A5088796006 @default.
• W2000394688 date "2008-12-01" @default.
• W2000394688 modified "2023-09-27" @default.
• W2000394688 title "Substitution features in the isomorphous replacement series for metal-organic compounds (NbxTa1−x)4O2(OMe)14(ReO4)2, x=0.7, 0.5, 0.3—Single-source precursors of complex oxides with organized porosity" @default.
• W2000394688 cites W148796242 @default.
• W2000394688 cites W1644268379 @default.
• W2000394688 cites W1980444624 @default.
• W2000394688 cites W1982985313 @default.
• W2000394688 cites W1985303199 @default.
• W2000394688 cites W1991542528 @default.
• W2000394688 cites W2000361710 @default.
• W2000394688 cites W2006261884 @default.
• W2000394688 cites W2009147376 @default.
• W2000394688 cites W2010608608 @default.
• W2000394688 cites W2012328204 @default.
• W2000394688 cites W2014870485 @default.
• W2000394688 cites W2021574712 @default.
• W2000394688 cites W2028709426 @default.
• W2000394688 cites W2028799667 @default.
• W2000394688 cites W2029146719 @default.
• W2000394688 cites W2037425562 @default.
• W2000394688 cites W2041257273 @default.
• W2000394688 cites W2044080285 @default.
• W2000394688 cites W2066241742 @default.
• W2000394688 cites W2077947338 @default.
• W2000394688 cites W2078263715 @default.
• W2000394688 cites W2083672452 @default.
• W2000394688 cites W2088019693 @default.
• W2000394688 cites W2092904771 @default.
• W2000394688 cites W2097402164 @default.
• W2000394688 cites W2115211013 @default.
• W2000394688 cites W2154849309 @default.
• W2000394688 cites W2162887361 @default.
• W2000394688 cites W2167590372 @default.
• W2000394688 cites W2167804188 @default.
• W2000394688 cites W2324840544 @default.
• W2000394688 cites W282435616 @default.
• W2000394688 cites W3137466007 @default.
• W2000394688 cites W399949088 @default.
• W2000394688 cites W57012802 @default.
• W2000394688 doi "https://doi.org/10.1016/j.jssc.2008.09.003" @default.
• W2000394688 hasPublicationYear "2008" @default.
• W2000394688 type Work @default.
• W2000394688 sameAs 2000394688 @default.
• W2000394688 citedByCount "9" @default.
• W2000394688 countsByYear W20003946882012 @default.
• W2000394688 countsByYear W20003946882013 @default.
• W2000394688 countsByYear W20003946882014 @default.
• W2000394688 countsByYear W20003946882015 @default.
• W2000394688 countsByYear W20003946882018 @default.
• W2000394688 countsByYear W20003946882021 @default.
• W2000394688 countsByYear W20003946882022 @default.
• W2000394688 crossrefType "journal-article" @default.
• W2000394688 hasAuthorship W2000394688A5036513853 @default.
• W2000394688 hasAuthorship W2000394688A5081897272 @default.
• W2000394688 hasAuthorship W2000394688A5088796006 @default.
• W2000394688 hasConcept C120665830 @default.
• W2000394688 hasConcept C121332964 @default.
• W2000394688 hasConcept C127313418 @default.
• W2000394688 hasConcept C143724316 @default.
• W2000394688 hasConcept C151730666 @default.
• W2000394688 hasConcept C178790620 @default.
• W2000394688 hasConcept C179104552 @default.
• W2000394688 hasConcept C185592680 @default.
• W2000394688 hasConcept C199360897 @default.
• W2000394688 hasConcept C207114421 @default.
• W2000394688 hasConcept C2778220771 @default.
• W2000394688 hasConcept C41008148 @default.
• W2000394688 hasConcept C50515024 @default.
• W2000394688 hasConcept C544153396 @default.
• W2000394688 hasConcept C71240020 @default.
• W2000394688 hasConcept C8010536 @default.
• W2000394688 hasConceptScore W2000394688C120665830 @default.
• W2000394688 hasConceptScore W2000394688C121332964 @default.
• W2000394688 hasConceptScore W2000394688C127313418 @default.
• W2000394688 hasConceptScore W2000394688C143724316 @default.
• W2000394688 hasConceptScore W2000394688C151730666 @default.
• W2000394688 hasConceptScore W2000394688C178790620 @default.
• W2000394688 hasConceptScore W2000394688C179104552 @default.
• W2000394688 hasConceptScore W2000394688C185592680 @default.
• W2000394688 hasConceptScore W2000394688C199360897 @default.
• W2000394688 hasConceptScore W2000394688C207114421 @default.
• W2000394688 hasConceptScore W2000394688C2778220771 @default.
• W2000394688 hasConceptScore W2000394688C41008148 @default.
• W2000394688 hasConceptScore W2000394688C50515024 @default.
• W2000394688 hasConceptScore W2000394688C544153396 @default.
• W2000394688 hasConceptScore W2000394688C71240020 @default.
• W2000394688 hasConceptScore W2000394688C8010536 @default.
• W2000394688 hasIssue "12" @default.
• W2000394688 hasLocation W20003946881 @default.
• W2000394688 hasOpenAccess W2000394688 @default.
• W2000394688 hasPrimaryLocation W20003946881 @default.
• W2000394688 hasRelatedWork W2029913809 @default.
• W2000394688 hasRelatedWork W2056542950 @default.

• next