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- W2000397241 abstract "The ammonolysis of tetrakistrifluoromethyldiarsine probably proceeds through solvolytic fission of the As—As bond. Solvolysis of the diarsine by sodium methoxide in methanol does not seem to proceed by this mechanism. Chlorobistrifiuoromethylarsine is stable to ethanol and ethanethiol below 110° but reacts violently with solid sodium alcoholates to give only decomposition products. With solid sodium mercaptide chlorobistrifluoromethylarsine yields ethylmercaptobistrifiuoromethylarsine. This mercapto-arsine is also obtained by reacting iodobistrifluoromethylarsine with mercuric mercaptide. Ammonolysis and hydrolysis studies of the compounds R 2 AsCF 3 and RAs(CF 3 ) 2 (R = C 2 H 5 , C 4 H 9 ) indicate that the mechanism of solvolysis could be S N 2." @default.
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- W2000397241 date "1962-04-01" @default.
- W2000397241 modified "2023-09-23" @default.
- W2000397241 title "PERFLUOROALKYL ARSENICALS: PART V. SOME SOLVOLYSIS STUDIES" @default.
- W2000397241 cites W2115933330 @default.
- W2000397241 doi "https://doi.org/10.1139/v62-092" @default.
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