Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000404105> ?p ?o ?g. }
- W2000404105 endingPage "4148" @default.
- W2000404105 startingPage "4142" @default.
- W2000404105 abstract "The availability of iron has been thought to be a main limiting factor for the productivity of phytoplankton and related with the uptake of atmospheric CO2 and algal blooms in fresh and sea waters. In this work, the formation of bioavailable iron (Fe(II)aq) from the dissolution of iron oxide particles was investigated in the ice phase under both UV and visible light irradiation. The photoreductive dissolution of iron oxides proceeded slowly in aqueous solution (pH 3.5) but was significantly accelerated in polycrystalline ice, subsequently releasing more bioavailable ferrous iron upon thawing. The enhanced photogeneration of Fe(II)aq in ice was confirmed regardless of the type of iron oxides [hematite, maghemite (γ-Fe2O3), goethite (α-FeOOH)] and the kind of electron donors. The ice-enhanced dissolution of iron oxides was also observed under visible light irradiation, although the dissolution rate was much slower compared with the case of UV radiation. The iron oxide particles and organic electron donors (if any) in ice are concentrated and aggregated in the liquid-like grain boundary region (freeze concentration effect) where protons are also highly concentrated (lower pH). The enhanced photodissolution of iron oxides should occur in this confined boundary region. We hypothesized that electron hopping through the interconnected grain boundaries of iron oxide particles facilitates the separation of photoinduced charge pairs. The outdoor experiments carried out under ambient solar radiation of Ny-Ålesund (Svalbard, 78°55′N) also showed that the generation of dissolved Fe(II)aq via photoreductive dissolution is enhanced when iron oxides are trapped in ice. Our results imply that the ice(snow)-covered surfaces and ice-cloud particles containing iron-rich mineral dusts in the polar and cold environments provide a source of bioavailable iron when they thaw." @default.
- W2000404105 created "2016-06-24" @default.
- W2000404105 creator A5003119642 @default.
- W2000404105 creator A5061008674 @default.
- W2000404105 creator A5064690703 @default.
- W2000404105 creator A5074893258 @default.
- W2000404105 creator A5078307783 @default.
- W2000404105 date "2010-05-06" @default.
- W2000404105 modified "2023-09-23" @default.
- W2000404105 title "Photoreductive Dissolution of Iron Oxides Trapped in Ice and Its Environmental Implications" @default.
- W2000404105 cites W13722102 @default.
- W2000404105 cites W1538561477 @default.
- W2000404105 cites W1637244524 @default.
- W2000404105 cites W1972707614 @default.
- W2000404105 cites W1975562743 @default.
- W2000404105 cites W1977481238 @default.
- W2000404105 cites W1979946377 @default.
- W2000404105 cites W1987455873 @default.
- W2000404105 cites W1990555060 @default.
- W2000404105 cites W1993013648 @default.
- W2000404105 cites W2004442026 @default.
- W2000404105 cites W2006946243 @default.
- W2000404105 cites W2015034340 @default.
- W2000404105 cites W2015465699 @default.
- W2000404105 cites W2021628727 @default.
- W2000404105 cites W2025379350 @default.
- W2000404105 cites W2027516016 @default.
- W2000404105 cites W2035265108 @default.
- W2000404105 cites W2043163241 @default.
- W2000404105 cites W2047988525 @default.
- W2000404105 cites W2052419798 @default.
- W2000404105 cites W2061341720 @default.
- W2000404105 cites W2064040135 @default.
- W2000404105 cites W2078388384 @default.
- W2000404105 cites W2091235181 @default.
- W2000404105 cites W2093871642 @default.
- W2000404105 cites W2098205015 @default.
- W2000404105 cites W2100667474 @default.
- W2000404105 cites W2102337248 @default.
- W2000404105 cites W2105796581 @default.
- W2000404105 cites W2165806421 @default.
- W2000404105 cites W2170735318 @default.
- W2000404105 cites W2789272273 @default.
- W2000404105 cites W72372629 @default.
- W2000404105 doi "https://doi.org/10.1021/es9037808" @default.
- W2000404105 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20446731" @default.
- W2000404105 hasPublicationYear "2010" @default.
- W2000404105 type Work @default.
- W2000404105 sameAs 2000404105 @default.
- W2000404105 citedByCount "95" @default.
- W2000404105 countsByYear W20004041052012 @default.
- W2000404105 countsByYear W20004041052013 @default.
- W2000404105 countsByYear W20004041052014 @default.
- W2000404105 countsByYear W20004041052015 @default.
- W2000404105 countsByYear W20004041052016 @default.
- W2000404105 countsByYear W20004041052017 @default.
- W2000404105 countsByYear W20004041052018 @default.
- W2000404105 countsByYear W20004041052019 @default.
- W2000404105 countsByYear W20004041052020 @default.
- W2000404105 countsByYear W20004041052021 @default.
- W2000404105 countsByYear W20004041052022 @default.
- W2000404105 countsByYear W20004041052023 @default.
- W2000404105 crossrefType "journal-article" @default.
- W2000404105 hasAuthorship W2000404105A5003119642 @default.
- W2000404105 hasAuthorship W2000404105A5061008674 @default.
- W2000404105 hasAuthorship W2000404105A5064690703 @default.
- W2000404105 hasAuthorship W2000404105A5074893258 @default.
- W2000404105 hasAuthorship W2000404105A5078307783 @default.
- W2000404105 hasConcept C147789679 @default.
- W2000404105 hasConcept C150394285 @default.
- W2000404105 hasConcept C178790620 @default.
- W2000404105 hasConcept C179104552 @default.
- W2000404105 hasConcept C185592680 @default.
- W2000404105 hasConcept C191897082 @default.
- W2000404105 hasConcept C192562407 @default.
- W2000404105 hasConcept C199289684 @default.
- W2000404105 hasConcept C2775832776 @default.
- W2000404105 hasConcept C2777697756 @default.
- W2000404105 hasConcept C2777781897 @default.
- W2000404105 hasConcept C2777787761 @default.
- W2000404105 hasConcept C2779131772 @default.
- W2000404105 hasConcept C2779851234 @default.
- W2000404105 hasConcept C2780191927 @default.
- W2000404105 hasConcept C2780786144 @default.
- W2000404105 hasConcept C88380143 @default.
- W2000404105 hasConceptScore W2000404105C147789679 @default.
- W2000404105 hasConceptScore W2000404105C150394285 @default.
- W2000404105 hasConceptScore W2000404105C178790620 @default.
- W2000404105 hasConceptScore W2000404105C179104552 @default.
- W2000404105 hasConceptScore W2000404105C185592680 @default.
- W2000404105 hasConceptScore W2000404105C191897082 @default.
- W2000404105 hasConceptScore W2000404105C192562407 @default.
- W2000404105 hasConceptScore W2000404105C199289684 @default.
- W2000404105 hasConceptScore W2000404105C2775832776 @default.
- W2000404105 hasConceptScore W2000404105C2777697756 @default.
- W2000404105 hasConceptScore W2000404105C2777781897 @default.
- W2000404105 hasConceptScore W2000404105C2777787761 @default.
- W2000404105 hasConceptScore W2000404105C2779131772 @default.