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- W2000405139 abstract "In the solvent extraction studies of trivalent Am, Cm, La, Eu and Lu using thenoyltrifluoroacetone (HTTA) in xylene as the extractant, the pH variation experiments at a fixed extractant concentration revealed a reduction in slope from three to two when log D was plotted vs pH. While the plots of log D vs log [HTTA]org gave slopes of three at lower pH values, those at higher pH values showed a slope of two, thus suggesting the extraction of hydroxo chelates MOH(TTA)2 in the higher pH region. The points of intersection of the lines of slopes three and two in the log D vs pH plots are not affected significantly by the nature and concentration of the extractant, and these are shown to be numerically equal to the negative logarithm of the first hydrolysis constants Kh, whose values increase with decreasing ionic radii of the metal ions. The changes in the Kh values on varying ionic strength are as expected from a known empirical relation." @default.
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- W2000405139 date "1989-01-01" @default.
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- W2000405139 title "Hydrolysis of actinides and lanthanides: hydrolysis of some trivalent actinide and lanthanide ions studied by extraction with thenoyltrifluoroacetone" @default.
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- W2000405139 doi "https://doi.org/10.1016/s0277-5387(00)80506-9" @default.
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