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- W2000405181 abstract "The solvation Gibbs and Helmholtz energies are evaluated exactly in two model systems. One is a modification of an interstitial model for water, the second is a non ideal gas mixture within the second virial approximation. In both systems the general form of the solvation Gibbs energy of a large solute s is ΔGs* =aVs +bAs whereVs andAs are the volume and surface area of the solute s. We also show that this general form is likely to hold true in any real solution." @default.
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- W2000405181 date "1994-08-01" @default.
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- W2000405181 title "Solvation of large molecules: Some exact results on the dependence on volume and surface area of the solute" @default.
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- W2000405181 doi "https://doi.org/10.1016/0301-4622(94)00041-7" @default.
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