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- W2000406116 abstract "A system of polymer chains grafted onto an inert planar surface to form a monolayer has been studied. It has been shown by evaluating the forces acting on each monomeric unit that the magnitude of the elongating force increases linearly with the distance of the unit from the surface. An analogy has been found between the behaviour of chains in the monolayer and chains subject to a longitudinal hydrodynamic field at a critical value of gradient; the latter lies in the middle of the phase transition coil-extended chain. The polymeric monolayer is a system stable inside the phase transition region. Reasons are pointed out that show the fallacy of the blob concept which considers the monolayer to be a weakly fluctiating system." @default.
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- W2000406116 date "1990-01-01" @default.
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- W2000406116 title "Analogy between a macromolecule in a hydrodynamic field and in a polymeric monolayer" @default.
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- W2000406116 doi "https://doi.org/10.1016/0032-3950(90)90088-n" @default.
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