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- W2000406342 abstract "Two different multilayer structures composed of ten alternating Ni and Al thin films were sputter deposited on Si (111) substrates. These multilayers with individual Ni and Al thin film thicknesses of about 25 nm and 38 nm and of 25 nm and 13 nm, respectively, have the average compositions of Ni0.50Al0.50 and Ni0.75Al0.25. The samples were heat treated in a differential scanning calorimeter instrument with a constant heating rate of 40 °C min −1 in Ar from room temperature to 550 °C. The compositions of as-deposited and heat-treated samples were studied with high-resolution Auger electron spectroscopy (AES) rotational depth profiling. X-ray photoelectron spectroscopy (XPS) analyses show an excess of Ni in both annealed samples. X-ray diffraction measurements of annealed multilayers show the formation of Ni2Al3 and NiAl3 phases in the Ni0.50Al0.50 sample and the presence of Ni3Al and Ni A13 phases with some excess of Ni in the Ni0.75Al0.75 sample. AES and XPS investigations of the reacted layers after 15 min annealing in air at 500 °C disclose considerably different surface oxide thin films: on the Ni0.50Al0.50 layer the oxide thin film consists of Al2O3 with a small amount of NiO, whereas that on the top of the Ni0.75Al0.25 layer is thicker and consists of NiO on top and some Al2O3 below." @default.
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- W2000406342 date "1995-12-01" @default.
- W2000406342 modified "2023-10-18" @default.
- W2000406342 title "Characterization of intermetallic phases and oxides formed in annealed multilayer structures" @default.
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- W2000406342 doi "https://doi.org/10.1016/0040-6090(95)06925-9" @default.
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