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- W2000408685 abstract "Rare earth-substituted lead apatites of the Pb10−2xLnxMx(PO4)6Y2(Ln = La, Nd, Eu, Gd, Dy, and Y: M = Na and K; Y = F and Cl) systems were prepared and studied by X-ray diffraction and infrared methods. The powder patterns of all the compounds show the apatite-like hexagonal structure. Singlecrystal precession data reveal that the space group of the Pb6Ln2Na2(PO4)6F2 compounds is probably P6 while that of Pb6Ln2K2(PO4)6F2 is P63m. Analysis of the ir spectra of substituted Ca, Ba, and Pb compounds show the effect of substituted ions on the spectra and support the assumption that substitution in the Ba and Pb systems is an ordered process. Ordering of the substituted ions in the systems studied is discussed in view of changes in lattice parameters, size conditions, and polarizing properties of the ions." @default.
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- W2000408685 date "1980-09-01" @default.
- W2000408685 modified "2023-10-18" @default.
- W2000408685 title "Lead phosphate apatites substituted by rare earth, sodium, and potassium ions" @default.
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- W2000408685 doi "https://doi.org/10.1016/0022-4596(80)90225-x" @default.
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