Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000408918> ?p ?o ?g. }
Showing items 1 to 66 of
66
with 100 items per page.
- W2000408918 endingPage "2064" @default.
- W2000408918 startingPage "2047" @default.
- W2000408918 abstract "Different types of nonionic, water-soluble polymers and macromonomers are investigated as emulsion stabilizers in the batch emulsion polymerization of styrene. A power law dependence of the rate of polymerization vs. stabilizer concentration is observed, in formal accordance to Smith-Ewart kinetics. For water-soluble polymers, exponents in the range of 0,6 are found which are close to that of the reference anionic surfactant (0,67). The differences are mainly attributed to the larger initial particle size which is accompanied by secondary agglomeration during polymerization. Several reasons for this agglomeration are discussed which have their origin in the solution and adsorption properties of the water-soluble polymers. Compared to the non-functional polymers some macromonomers show a similar kinetic behavior with exponents in the range of 0,4 to 0,5, while others give very small values. These differences strongly depend on the molecular structure of the macromonomers. They are in particular attributed to enhanced homopolymerization as well as solubility in monomer and polymer. No secondary agglomeration takes place when using macromonomers as emulsion stabilizers. This is due to the enhanced colloidal stability because of the defined bonding of the macromonomers to the latex particle surface as compared to the more random grafting of the non-functional water-soluble polymers." @default.
- W2000408918 created "2016-06-24" @default.
- W2000408918 creator A5022238074 @default.
- W2000408918 creator A5032381880 @default.
- W2000408918 creator A5042635995 @default.
- W2000408918 date "1995-06-01" @default.
- W2000408918 modified "2023-09-27" @default.
- W2000408918 title "Steric stabilization by grafting and copolymerization of water-soluble oligomers and polymers" @default.
- W2000408918 doi "https://doi.org/10.1002/macp.1995.021960624" @default.
- W2000408918 hasPublicationYear "1995" @default.
- W2000408918 type Work @default.
- W2000408918 sameAs 2000408918 @default.
- W2000408918 citedByCount "18" @default.
- W2000408918 countsByYear W20004089182012 @default.
- W2000408918 countsByYear W20004089182017 @default.
- W2000408918 countsByYear W20004089182018 @default.
- W2000408918 countsByYear W20004089182021 @default.
- W2000408918 crossrefType "journal-article" @default.
- W2000408918 hasAuthorship W2000408918A5022238074 @default.
- W2000408918 hasAuthorship W2000408918A5032381880 @default.
- W2000408918 hasAuthorship W2000408918A5042635995 @default.
- W2000408918 hasConcept C127413603 @default.
- W2000408918 hasConcept C15920480 @default.
- W2000408918 hasConcept C166940927 @default.
- W2000408918 hasConcept C178790620 @default.
- W2000408918 hasConcept C185592680 @default.
- W2000408918 hasConcept C188027245 @default.
- W2000408918 hasConcept C192562407 @default.
- W2000408918 hasConcept C199002037 @default.
- W2000408918 hasConcept C2777492985 @default.
- W2000408918 hasConcept C42360764 @default.
- W2000408918 hasConcept C44228677 @default.
- W2000408918 hasConcept C521977710 @default.
- W2000408918 hasConceptScore W2000408918C127413603 @default.
- W2000408918 hasConceptScore W2000408918C15920480 @default.
- W2000408918 hasConceptScore W2000408918C166940927 @default.
- W2000408918 hasConceptScore W2000408918C178790620 @default.
- W2000408918 hasConceptScore W2000408918C185592680 @default.
- W2000408918 hasConceptScore W2000408918C188027245 @default.
- W2000408918 hasConceptScore W2000408918C192562407 @default.
- W2000408918 hasConceptScore W2000408918C199002037 @default.
- W2000408918 hasConceptScore W2000408918C2777492985 @default.
- W2000408918 hasConceptScore W2000408918C42360764 @default.
- W2000408918 hasConceptScore W2000408918C44228677 @default.
- W2000408918 hasConceptScore W2000408918C521977710 @default.
- W2000408918 hasIssue "6" @default.
- W2000408918 hasLocation W20004089181 @default.
- W2000408918 hasOpenAccess W2000408918 @default.
- W2000408918 hasPrimaryLocation W20004089181 @default.
- W2000408918 hasRelatedWork W1548483205 @default.
- W2000408918 hasRelatedWork W1975106166 @default.
- W2000408918 hasRelatedWork W2033994495 @default.
- W2000408918 hasRelatedWork W2034998800 @default.
- W2000408918 hasRelatedWork W2063884667 @default.
- W2000408918 hasRelatedWork W2083617650 @default.
- W2000408918 hasRelatedWork W2107076875 @default.
- W2000408918 hasRelatedWork W2108456125 @default.
- W2000408918 hasRelatedWork W2111188715 @default.
- W2000408918 hasRelatedWork W2140369949 @default.
- W2000408918 hasVolume "196" @default.
- W2000408918 isParatext "false" @default.
- W2000408918 isRetracted "false" @default.
- W2000408918 magId "2000408918" @default.
- W2000408918 workType "article" @default.