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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000420610> ?p ?o ?g. }

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• W2000420610 abstract "A total synthesis of daunosamine (3) and acosamine (4) has been accomplished via a diastereoselective intramolecular nitrone-olefin cyclization. In the key step the chiral nitrone 12a cyclized to give two isoxazolidines 13a and 14a in an 82:18 ratio. Further elaboration of 13a led to daunosamine and acosamine. The effects of olefin substitution on the diastereoselectivity of the cycloaddition was also examined." @default.
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• W2000420610 modified "2023-10-15" @default.
• W2000420610 title "Total synthesis of acosamine and daunosamine utilizing a diastereoselective intramolecular [3+2] cycloaddition" @default.
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• W2000420610 doi "https://doi.org/10.1016/s0040-4020(01)96700-6" @default.
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