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• W2000421897 abstract "The absolute configurations of a broad spectrum of aryl alcohols 1 have been determined for the first time by the CD exciton chirality method. The configurational assignment is additionally verified by computer modeling and lipase-catalyzed acetylation of the racemic alcohols. The CD-spectroscopic data have revealed that the S enantiomers of the benzoate derivatives 2 display a positive first Cotton effect and the R enantiomers a negative one at around 228 nm. Thus, the sense of the first Cotton effect of the benzoate derivative 2 allows a reliable assignment of the absolute configuration of the corresponding alcohol 1." @default.
• W2000421897 created "2016-06-24" @default.
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• W2000421897 date "1999-12-10" @default.
• W2000421897 modified "2023-09-30" @default.
• W2000421897 title "Microscale Determination of the Absolute Configuration of α-Aryl-Substituted Alcohols by the CD Exciton Chirality Method" @default.
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• W2000421897 doi "https://doi.org/10.1021/jo991424i" @default.
• W2000421897 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/10813914" @default.
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