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- W2000425581 abstract "meso-Substituent effect on the redox properties of octaethylporphyrin and its zinc(II) and copper(II) complexes are investigated with cyclic volatmmetry. The E12, values were observed to correlate linearly with Hammett's σp constant for the first and second oxidation reaction and the first reduction reaction in the metallo-OEP series, with ρ values an order of magnitude larger than that of the TPP series. For the free base OEP series, steric effect has to be taken into consideration when discussing the meso-substituent effect of OEP's in addition to electronic effect." @default.
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- W2000425581 title "Substituent effect on the redox potential of -substituted octaethylporphyrins and their zinc and copper complexes" @default.
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- W2000425581 doi "https://doi.org/10.1016/s0040-4020(01)85461-2" @default.
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