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- W2000429892 abstract "Ruthenium thiolates [cpRu(PR′ 3 ) 2 (SR)] (PR′ 3 = PPh 3 ,1/2 dppe, 1/2 dppm, R = Me, CH 2 Ph) are obtained from the corresponding chlorides and NaSR. PPh 3 is readily exchanged for CO to give the chiral complexes [cpRu(PPh 3 )(CO)(SR)]. Alkylation with methyl tosylate yields the cations [cpRu(dppe)(SMeR)] + and [cpRu(PPh 3 )(CO)(SMeR)] + , which were isolated as their PF 6 - salts. The neutral carbonyls add dimethyl acetylenedicarboxylate giving five-membered metallocycles." @default.
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- W2000429892 date "1990-11-01" @default.
- W2000429892 modified "2023-09-26" @default.
- W2000429892 title "Elektronenreiche Ruthenium-Thiolat-Komplexe, Synthese und Reaktionen mit Elektrophilen / Electron-Rich Ruthenium Thiolate Complexes, Synthesis and Reactions with Electrophiles" @default.
- W2000429892 doi "https://doi.org/10.1515/znb-1990-1105" @default.
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