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- W2000437211 abstract "Structurally characterised 17-vertex [(PMe2Ph)2PtB16H17Me] 3 is obtained, albeit in low yield, by platination of 16-vertex B16H20 1 using [PtMe2(PMe2Ph)2] under mild conditions. Platination has occurred on the {B10} subcluster of 1, interesting in that B16H20 itself deprotonates on the {B8} subcluster: the reference 16-vertex [B16H19]- anion 1a, prepared by deprotonation of 1 with 1,8-bis(dimethylamino)naphthalene, is also structurally characterised. [PtMe2(PMe2Ph)2] with 14-vertex B14H18 2 similarly gives a low yield of 15-vertex [(PMe2Ph)2PtB14H16] 5, of formulation and structure substantiated by DFT calculations." @default.
- W2000437211 created "2016-06-24" @default.
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- W2000437211 date "2005-01-01" @default.
- W2000437211 modified "2023-10-14" @default.
- W2000437211 title "Macropolyhedral boron-containing cluster chemistry. The reaction of B<sub>16</sub>H<sub>20</sub>and B<sub>14</sub>H<sub>18</sub>with [PtMe<sub>2</sub>(PMe<sub>2</sub>Ph)<sub>2</sub>] to give [(PMe<sub>2</sub>Ph)<sub>2</sub>PtB<sub>16</sub>H<sub>17</sub>Me] and [(PMe<sub>2</sub>Ph)<sub>2</sub>PtB<sub>14</sub>H<sub>16</sub>]" @default.
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- W2000437211 doi "https://doi.org/10.1039/b419241a" @default.
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