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- W2000438373 abstract "Non-linear regressions were applied to n-alkanes retention data for the determination of gas hold-up in a preceding paper. It was found that at temperatures over 100 degrees C the reduced partial molar free energy of solution, deltaG/RT, tends to be negligible for the solute methane in poly(dimethylsiloxane) stationary phases. A consequence of interest can be inferred from this fact. The C-H bonds from terminal methyl groups of n-alkane solute molecules should not contribute significantly to deltaG/RT in these conditions. The analysis of data confirms that, within the chromatographic experimental error, the contributions of n-alkane end C-H bonds are also negligible in this temperature range. Consequently, the regression parameter that contains the phase ratio of the column only includes the gas hold-up as the accompanying factor." @default.
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- W2000438373 date "2000-03-01" @default.
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- W2000438373 title "Interpreting the gas chromatographic retention of n-alkanes" @default.
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- W2000438373 doi "https://doi.org/10.1016/s0021-9673(99)01306-0" @default.
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