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- W2000438451 abstract "Wide angle X-ray diffraction patterns have been obtained at different temperatures between Tg + 100 and Tg − 300 K for three amorphous polymers very different in their chemical structure. These are poly (vinyl chloride) (vinylic), poly (vinyl methyl ether) (vinylic with a side group extending from the backbone) and poly (2-hydroxypropylether of bisphenol A) (no side groups). The interpretation has focused on the variation in the position of the diffraction maxima corresponding to interchain structural correlations. This temperature evolution shows two discontinuities: one is at the glass transition temperature for the material in question and the second is observed at a temperature approximately 100 K less than Tg. For all of the polymers studied the average structure is frozen below the temperature of the second discontinuity." @default.
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- W2000438451 date "1998-07-01" @default.
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- W2000438451 title "Study of interchain structural correlations in glassy polymers by X-ray diffraction" @default.
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- W2000438451 doi "https://doi.org/10.1016/s0022-3093(98)00422-0" @default.
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