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• W2000438489 abstract "The voltammetric behaviour in alkaline solution of a nickel-based chemically modified electrode (poly-NiTMHPP) prepared by oxidative electropolymerization of a nickel tetrakis(3-methoxy-4-hydroxyphenyl)porphyrin for electro-oxidation of methanol was investigated by cyclic voltammetry and the rotating disk technique. The oxidation of methanol occurs at 0.61 V vs. SCE, where oxidation is not observed at the bare electrode. The dependence of the oxidation current on the methanol concentration and on the number of redox centres Ni(II)/Ni(III) is discussed. From the fact that the oxidation current increases with increasing film thickness it is evident that the electrocatalytic reaction occurs inside the polymer film. The system examined is a typical example of a redox polymer with 3D properties. It is also concluded that the reaction mechanism of methanol electro-oxidation is of the so-called “R” case, according to the concept of Saveant and Andrieux, i.e. a cross-exchange reaction is the limiting step." @default.
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• W2000438489 date "1997-04-01" @default.
• W2000438489 modified "2023-10-17" @default.
• W2000438489 title "Glassy carbon electrode modified by conductive, polymeric nickel(II) porphyrin complex as a 3D homogeneous catalytic system for methanol oxidation in basic media" @default.
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• W2000438489 doi "https://doi.org/10.1016/s0022-0728(96)04976-5" @default.
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