FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000441415> ?p ?o ?g. }

• W2000441415 endingPage "145" @default.
• W2000441415 startingPage "139" @default.
• W2000441415 abstract "Two imidazolin-2-imine zinc complexes [Zn(8MeBL)Cl2] (1) and [Zn(8MeBL)(OAc)2] (2) were synthesised, completely characterised and investigated for their activity in the solvent-free ring-opening polymerisation of d,l-lactide. It could be shown that these compounds are able to act as efficient initiators for lactide polymerisation, and polylactides with molecular weights (Mw) of around 23,000–55,000 g/mol could be obtained with relatively narrow polydispersities. 1 and 2 exhibit an advantageous combination of robustness towards humidity and high activity in the polymer melt. A comparative DFT study on 1 and 2 and their guanidine counterparts revealed that the two complex series possess a strikingly similar electronic structure. Although the imidazolin-2-imine is more basic, its zinc complexes have only a slightly greater positive charge on the zinc atom in comparison to the corresponding guanidine complexes. Accordingly, their activity in the initiation of the ring-opening polymerisation is increased which is directly related to the Lewis acidity of the zinc atom. These findings allow more insights into the mechanism of the lactide polymerisation with neutral N-donor stabilised zinc complexes." @default.
• W2000441415 created "2016-06-24" @default.
• W2000441415 creator A5009620443 @default.
• W2000441415 creator A5023844948 @default.
• W2000441415 creator A5029172893 @default.
• W2000441415 creator A5029225816 @default.
• W2000441415 creator A5036558577 @default.
• W2000441415 creator A5038239716 @default.
• W2000441415 creator A5059713648 @default.
• W2000441415 creator A5087967838 @default.
• W2000441415 creator A5088267663 @default.
• W2000441415 date "2010-02-01" @default.
• W2000441415 modified "2023-10-18" @default.
• W2000441415 title "New insights into the lactide polymerisation with neutral N-donor stabilised zinc complexes: Comparison of imidazolin-2-imine vs. guanidine complexes" @default.
• W2000441415 cites W1553692161 @default.
• W2000441415 cites W1976035418 @default.
• W2000441415 cites W1984201080 @default.
• W2000441415 cites W1984599229 @default.
• W2000441415 cites W1984614201 @default.
• W2000441415 cites W1985570466 @default.
• W2000441415 cites W1993331669 @default.
• W2000441415 cites W1995595540 @default.
• W2000441415 cites W1996874415 @default.
• W2000441415 cites W2010143048 @default.
• W2000441415 cites W2015784993 @default.
• W2000441415 cites W2019684777 @default.
• W2000441415 cites W2021795513 @default.
• W2000441415 cites W2023271753 @default.
• W2000441415 cites W2027753580 @default.
• W2000441415 cites W2035200786 @default.
• W2000441415 cites W2037981204 @default.
• W2000441415 cites W2038767330 @default.
• W2000441415 cites W2041546233 @default.
• W2000441415 cites W2042203406 @default.
• W2000441415 cites W2044154274 @default.
• W2000441415 cites W2050642967 @default.
• W2000441415 cites W2050674459 @default.
• W2000441415 cites W2055956577 @default.
• W2000441415 cites W2068322462 @default.
• W2000441415 cites W2078163251 @default.
• W2000441415 cites W2079607301 @default.
• W2000441415 cites W2082264584 @default.
• W2000441415 cites W2083376439 @default.
• W2000441415 cites W2089292867 @default.
• W2000441415 cites W2091746388 @default.
• W2000441415 cites W2092337099 @default.
• W2000441415 cites W2121894359 @default.
• W2000441415 cites W2132409397 @default.
• W2000441415 cites W2143981217 @default.
• W2000441415 cites W2160466249 @default.
• W2000441415 cites W2325367186 @default.
• W2000441415 cites W3205039858 @default.
• W2000441415 cites W2729228882 @default.
• W2000441415 doi "https://doi.org/10.1016/j.molcata.2009.10.012" @default.
• W2000441415 hasPublicationYear "2010" @default.
• W2000441415 type Work @default.
• W2000441415 sameAs 2000441415 @default.
• W2000441415 citedByCount "56" @default.
• W2000441415 countsByYear W20004414152012 @default.
• W2000441415 countsByYear W20004414152013 @default.
• W2000441415 countsByYear W20004414152014 @default.
• W2000441415 countsByYear W20004414152015 @default.
• W2000441415 countsByYear W20004414152016 @default.
• W2000441415 countsByYear W20004414152017 @default.
• W2000441415 countsByYear W20004414152018 @default.
• W2000441415 countsByYear W20004414152019 @default.
• W2000441415 countsByYear W20004414152020 @default.
• W2000441415 countsByYear W20004414152022 @default.
• W2000441415 countsByYear W20004414152023 @default.
• W2000441415 crossrefType "journal-article" @default.
• W2000441415 hasAuthorship W2000441415A5009620443 @default.
• W2000441415 hasAuthorship W2000441415A5023844948 @default.
• W2000441415 hasAuthorship W2000441415A5029172893 @default.
• W2000441415 hasAuthorship W2000441415A5029225816 @default.
• W2000441415 hasAuthorship W2000441415A5036558577 @default.
• W2000441415 hasAuthorship W2000441415A5038239716 @default.
• W2000441415 hasAuthorship W2000441415A5059713648 @default.
• W2000441415 hasAuthorship W2000441415A5087967838 @default.
• W2000441415 hasAuthorship W2000441415A5088267663 @default.
• W2000441415 hasConcept C161790260 @default.
• W2000441415 hasConcept C166940927 @default.
• W2000441415 hasConcept C178790620 @default.
• W2000441415 hasConcept C185592680 @default.
• W2000441415 hasConcept C188027245 @default.
• W2000441415 hasConcept C2776573223 @default.
• W2000441415 hasConcept C2776743539 @default.
• W2000441415 hasConcept C2779463914 @default.
• W2000441415 hasConcept C44228677 @default.
• W2000441415 hasConcept C521977710 @default.
• W2000441415 hasConcept C535196362 @default.
• W2000441415 hasConceptScore W2000441415C161790260 @default.
• W2000441415 hasConceptScore W2000441415C166940927 @default.
• W2000441415 hasConceptScore W2000441415C178790620 @default.
• W2000441415 hasConceptScore W2000441415C185592680 @default.
• W2000441415 hasConceptScore W2000441415C188027245 @default.
• W2000441415 hasConceptScore W2000441415C2776573223 @default.
• W2000441415 hasConceptScore W2000441415C2776743539 @default.
• W2000441415 hasConceptScore W2000441415C2779463914 @default.

• next