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- W2000442281 endingPage "452" @default.
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- W2000442281 abstract "Early experiments and molecular simulations of PUFA favored a rigid arrangement of double bonds in U-shaped or extended conformations such as angle-iron or helical. Although results of recent solid-state NMR measurements and molecular simulations have confirmed the existence of these structural motifs, they portray an image of DHA (22:6n-3) as a highly flexible molecule with rapid transitions between large numbers of conformers on the time scale from picoseconds to hundreds of nanoseconds. The low barriers to torsional rotation about C-C bonds that link the cis-locked double bonds with the methylene carbons between them are responsible for this unusual flexibility. Both the amplitude and frequency of motion increase toward the terminal methyl group of DHA." @default.
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- W2000442281 date "2003-04-01" @default.
- W2000442281 modified "2023-09-29" @default.
- W2000442281 title "The structure of DHA in phospholipid membranes" @default.
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- W2000442281 doi "https://doi.org/10.1007/s11745-003-1082-0" @default.
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