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• W2000447689 abstract "It is presently shown that long chain (C14, C16, and C18) alkanoic (saturated fatty) acids can form magnetically oriented hexagonal phases in aqueous concentrated solutions in mixtures with tetrabutylammonium (TBAOH) as the counterion. The hexagonal phase occurred for a molar ratio, alkanoic acid/TBAOH, higher than 1, i.e., for an excess of fatty acid. The hexagonal phase melted to an isotropic phase (micelles) upon heating at a given temperature depending on the alkyl chain length. The self-orientation of the hexagonal phase occurred upon cooling from the high-temperature isotropic phase within the magnetic field. The long axis of the hexagonal phase was shown to self-orient parallel to the magnetic field as evidenced by deuterium solid-state NMR. This finding is expected to be of interest in the field of structural biology and materials chemistry for the synthesis of oriented materials." @default.
• W2000447689 created "2016-06-24" @default.
• W2000447689 creator A5048833645 @default.
• W2000447689 date "2010-03-23" @default.
• W2000447689 modified "2023-09-25" @default.
• W2000447689 title "Magnetic Self-Orientation of Lyotropic Hexagonal Phases Based on Long Chain Alkanoic (Fatty) Acids" @default.
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• W2000447689 doi "https://doi.org/10.1021/la100885e" @default.
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