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- W2000449378 abstract "[structure: see text] The new BIPI ligands are phosphinoimidazolines that can be electronically tuned in three different ligand regions to explore electronic effects in asymmetric catalysis. Their application to the asymmetric Heck reaction (AHR) in the creation of a chiral quaternary center is described. Enantioselectivity is shown for the first time to depend linearly on phosphine electron density. Changing the ligand basicity by variation of the R(2) or R(3) substituents reverses facial selectivity." @default.
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- W2000449378 date "2003-01-30" @default.
- W2000449378 modified "2023-10-14" @default.
- W2000449378 title "Probing Electronic Effects in the Asymmetric Heck Reaction with the BIPI Ligands" @default.
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- W2000449378 doi "https://doi.org/10.1021/ol0340179" @default.
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