Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000453476> ?p ?o ?g. }
Showing items 1 to 81 of
81
with 100 items per page.
- W2000453476 abstract "Cyclopentadienyl metal complexes have played important roles in chemistry owing to their unique structures and functional activities. Here we report the synthesis and characterization of an entirely new class of cyclopentadienyl (Cp) metal complexes ({eta}{sup 5}-C{sub 60}Ph{sub 5})MLn (MLn = Li, K, Tl, and Cu.PEt{sub 3}). In these molecules, the five Cp carbons represent one pentagon of C{sub 60}, isolated from the remaining 50 sp{sup 2} carbon atoms by five surrounding sp{sup 3} carbon atoms each bearing a phenyl group. The X-ray crystal structure analysis of the thallium complex Tl({eta}{sup 5}-C{sub 60}Ph{sub 5}).2.5THF revealed its unique and esthetically pleasing C{sub 5} symmetrical molecular structure with the phenyl groups forming a chiral propeller array. The thallium atom is deeply buried in the cavity created by the phenyl groups, bonding to the five Cp carbons ({eta}{sup 5}-coordination) with an averaged Tl-C distance of 2.87 A. The key finding that we made in this research was a remarkable 5-fold addition of an organocopper reagent to C{sub 60}, which stands in contrast to the monoaddition reaction of Grignard or organolithium reagents. 10 refs., 1 fig." @default.
- W2000453476 created "2016-06-24" @default.
- W2000453476 creator A5009380113 @default.
- W2000453476 creator A5013418333 @default.
- W2000453476 creator A5014946319 @default.
- W2000453476 date "2010-08-04" @default.
- W2000453476 modified "2023-10-01" @default.
- W2000453476 title "ChemInform Abstract: The First Pentahaptofullerene Metal Complexes." @default.
- W2000453476 cites W2951089925 @default.
- W2000453476 doi "https://doi.org/10.1002/chin.199714096" @default.
- W2000453476 hasPublicationYear "2010" @default.
- W2000453476 type Work @default.
- W2000453476 sameAs 2000453476 @default.
- W2000453476 citedByCount "0" @default.
- W2000453476 crossrefType "journal-article" @default.
- W2000453476 hasAuthorship W2000453476A5009380113 @default.
- W2000453476 hasAuthorship W2000453476A5013418333 @default.
- W2000453476 hasAuthorship W2000453476A5014946319 @default.
- W2000453476 hasConcept C115624301 @default.
- W2000453476 hasConcept C138973236 @default.
- W2000453476 hasConcept C149635348 @default.
- W2000453476 hasConcept C161790260 @default.
- W2000453476 hasConcept C178790620 @default.
- W2000453476 hasConcept C179104552 @default.
- W2000453476 hasConcept C181458950 @default.
- W2000453476 hasConcept C185592680 @default.
- W2000453476 hasConcept C2781311116 @default.
- W2000453476 hasConcept C32909587 @default.
- W2000453476 hasConcept C40875361 @default.
- W2000453476 hasConcept C41008148 @default.
- W2000453476 hasConcept C544153396 @default.
- W2000453476 hasConcept C559099789 @default.
- W2000453476 hasConcept C58312451 @default.
- W2000453476 hasConcept C71240020 @default.
- W2000453476 hasConcept C8010536 @default.
- W2000453476 hasConcept C91967747 @default.
- W2000453476 hasConceptScore W2000453476C115624301 @default.
- W2000453476 hasConceptScore W2000453476C138973236 @default.
- W2000453476 hasConceptScore W2000453476C149635348 @default.
- W2000453476 hasConceptScore W2000453476C161790260 @default.
- W2000453476 hasConceptScore W2000453476C178790620 @default.
- W2000453476 hasConceptScore W2000453476C179104552 @default.
- W2000453476 hasConceptScore W2000453476C181458950 @default.
- W2000453476 hasConceptScore W2000453476C185592680 @default.
- W2000453476 hasConceptScore W2000453476C2781311116 @default.
- W2000453476 hasConceptScore W2000453476C32909587 @default.
- W2000453476 hasConceptScore W2000453476C40875361 @default.
- W2000453476 hasConceptScore W2000453476C41008148 @default.
- W2000453476 hasConceptScore W2000453476C544153396 @default.
- W2000453476 hasConceptScore W2000453476C559099789 @default.
- W2000453476 hasConceptScore W2000453476C58312451 @default.
- W2000453476 hasConceptScore W2000453476C71240020 @default.
- W2000453476 hasConceptScore W2000453476C8010536 @default.
- W2000453476 hasConceptScore W2000453476C91967747 @default.
- W2000453476 hasLocation W20004534761 @default.
- W2000453476 hasOpenAccess W2000453476 @default.
- W2000453476 hasPrimaryLocation W20004534761 @default.
- W2000453476 hasRelatedWork W1977895416 @default.
- W2000453476 hasRelatedWork W1982213947 @default.
- W2000453476 hasRelatedWork W1990654257 @default.
- W2000453476 hasRelatedWork W1992013926 @default.
- W2000453476 hasRelatedWork W1992647839 @default.
- W2000453476 hasRelatedWork W2012900735 @default.
- W2000453476 hasRelatedWork W2019680506 @default.
- W2000453476 hasRelatedWork W2028528592 @default.
- W2000453476 hasRelatedWork W2033940783 @default.
- W2000453476 hasRelatedWork W2055863566 @default.
- W2000453476 hasRelatedWork W2062535017 @default.
- W2000453476 hasRelatedWork W2075344572 @default.
- W2000453476 hasRelatedWork W2092824742 @default.
- W2000453476 hasRelatedWork W2095868319 @default.
- W2000453476 hasRelatedWork W2100836071 @default.
- W2000453476 hasRelatedWork W2153382048 @default.
- W2000453476 hasRelatedWork W2769486232 @default.
- W2000453476 hasRelatedWork W2951335692 @default.
- W2000453476 hasRelatedWork W2953338712 @default.
- W2000453476 hasRelatedWork W3138887471 @default.
- W2000453476 isParatext "false" @default.
- W2000453476 isRetracted "false" @default.
- W2000453476 magId "2000453476" @default.
- W2000453476 workType "article" @default.