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- W2000453757 abstract "Starting from protected (S)-3-hydroxyglutarimide 2a, the asymmetric synthesis of (2R,3S)-CP-99,994 8 was achieved. The crucial steps were a neighboring group participation leading to pyrrolidino-aziridinium intermediate 25 and the subsequent regioselective ring-opening reaction. In the case where neighboring group participation was not involved, only the eliminated product 15 was obtained." @default.
- W2000453757 created "2016-06-24" @default.
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- W2000453757 date "2006-12-01" @default.
- W2000453757 modified "2023-10-14" @default.
- W2000453757 title "SN2 reaction of 2-substituted 3-piperidinol mesylate with retention of configuration: application to the asymmetric synthesis of (2R,3S)-CP-99,994" @default.
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- W2000453757 doi "https://doi.org/10.1016/j.tetasy.2006.12.009" @default.
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