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- W2000454145 abstract "Abstract Reactions of the trivacant polyoxotungstate Na 9 [A- α -PW 9 O 34 ]·7H 2 O with CuCl 2 ·2H 2 O and LnCl 3 (Ln = Sm III , Er III ) in the presence of 1,2-diaminopropane (dap) have led to two organic–inorganic hybrid Cu–Ln heterometallic polyoxotungstates [Cu(dap) 2 (H 2 O)][Cu(dap) 2 ] 4.5 [Sm( α -PW 11 O 39 ) 2 ]·5H 2 O ( 1 ) and [Cu(dap) 2 (H 2 O)][Cu(dap) 2 ] 4.5 [Er( α -PW 11 O 39 ) 2 ]·4H 2 O ( 2 ). 1 and 2 are isomorphic and display the 2D 5-connected sheet constructed from alternating bis(undecatungstophosphate)lanthanate [Ln( α -PW 11 O 39 ) 2 ] 11− units and [Cu(dap) 2 ] 2+ connectors, in which the [Ln( α -PW 11 O 39 ) 2 ] 11– subunits act as 5-connected nodes and adjacent 2D sheets show the –AAA– packing mode. Furthermore, their thermogravimetric analyses and magnetic susceptibilities have been investigated." @default.
- W2000454145 created "2016-06-24" @default.
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- W2000454145 date "2013-08-01" @default.
- W2000454145 modified "2023-09-26" @default.
- W2000454145 title "Two 2D Cu–Ln heterometallic polyoxometalate aggregates constructed from bis(undecatungstophosphate)lanthanate units and copper-complex bridges" @default.
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- W2000454145 doi "https://doi.org/10.1016/j.ica.2013.05.027" @default.
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