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- W2000457835 abstract "Abstract Reducing sugars and polyols are shown to form soluble stable complexes with a series of metal ions at alkaline pH. Several properties of an iron-fructose complex have been studied. The specific conditions of pH and concentrations of iron and fructose necessary for complex formation are described. Evidence for the existence of the complex is (a) its solubility at alkaline pH, (b) its characteristic spectral properties, (c) titration and redox measurements, and (d) the direct isolation of the water-soluble complex. Ferric-fructose can be isolated and purified by precipitation from an aqueous solution with ethanol or other organic solvents. Elemental analysis indicates the complex at pH 9.0 is formed with 2 Fe: 2 fructose: 1 Na. Ferric-fructose is a low-molecular-weight compound which rapidly dialyses through a Visking sac. It is isoionic at pH 4.5–4.7. Metal-sugar complexes may play an important biological role in the transport of the mineral elements across cell membranes." @default.
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- W2000457835 date "1963-01-01" @default.
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- W2000457835 title "Chelation of iron by sugars" @default.
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- W2000457835 doi "https://doi.org/10.1016/0006-3002(63)91264-2" @default.
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