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• W2000458033 abstract "Abstract A simplified version of Walsh's diagrams is proposed. Using this MO-based scheme, the angular geometry at dicoordinate and tricoordinate atoms in covalent molecules can be predicted, even when π bonding exists in the system. The basic “rule of thumb” developed in that distortion from the geometry of highest symmetry will occur only if the in-plane p orbital at the center of interest contains some antibonding, or appreciable nonbonding, electron density. These predictions are tested for a wide variety of molecules." @default.
• W2000458033 created "2016-06-24" @default.
• W2000458033 creator A5082779067 @default.
• W2000458033 date "1979-01-01" @default.
• W2000458033 modified "2023-09-24" @default.
• W2000458033 title "Geometry predictions for π-bonded molecules using simplified MO theory" @default.
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• W2000458033 doi "https://doi.org/10.1016/0040-4020(79)80063-0" @default.
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