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- W2000458277 abstract "“Carbonic acid cannot exist in the free state. ” Now, a surprisingly simple experiment has shown that this statement is wrong. Thermolysis of NH 4 HCO 3 affords, among other products, H 2 CO 3 , which is stable as both the neutral molecule and the radical cation. This finding also confirms the results of detailed ab initio and semiempirical calculations, which show that H 2 CO 3 should be stable in the gas phase because the activation energy for its decomposition is large." @default.
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- W2000458277 date "1987-04-01" @default.
- W2000458277 modified "2023-10-17" @default.
- W2000458277 title "Thermolysis of NH<sub>4</sub>HCO<sub>3</sub>—A Simple Route to the Formation of Free Carbonic Acid (H<sub>2</sub>CO<sub>3</sub>) in the Gas Phase" @default.
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- W2000458277 doi "https://doi.org/10.1002/anie.198703541" @default.
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