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- W2000459458 abstract "Diastereoisomerically pure N-Boc 2-acyloxazolidines were synthesized from phenylglyoxal and ethyl glyoxylate. Reaction of these heterocycles with Grignard reagents is highly stereoselective. Homochiral 1,2-diols were ultimately obtained after N-deprotection, hydrolysis and reduction of the intermediate α-hydroxy aldehyde. The asymmetric induction can be explained by a chelated model." @default.
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- W2000459458 title "Asymmetric synthesis of homochiral 1,2-diols via N-boc oxazolidines" @default.
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- W2000459458 doi "https://doi.org/10.1016/s0040-4039(00)76893-6" @default.
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