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- W2000462130 abstract "A new molybdenum arsenate, CoIII(en)3H3O[(CoIIO6)MoVI6O18(AsIII3O3)2]·2H2O, has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). The polyanion framework derives from the Anderson structure in which the central octahedron is filled up by a cobalt(II), and is capped on both sides by two cyclic As3O6 groups. The countercations contain a [Co(en)3]3+ complex cation and a proton hydrate H3O+. There are hydrogen bonds between the countercations and polyanions. A probe reaction of the oxidation of benzaldehyde with H2O2 shows that the title compound has high catalytic activity in the reaction." @default.
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- W2000462130 title "Hydrothermal synthesis and crystal structure of a new molybdenum(VI) arsenate(III), CoIII(en)3H3O[(CoIIO6)MoVI6O18(AsIII3O3)2]·2H2O" @default.
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- W2000462130 doi "https://doi.org/10.1016/s0020-1693(99)00382-5" @default.
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