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- W2000464294 abstract "Abstract The selective conversion of 2,2,2-trifluoro-1-furan-2-yl-ethanone into ( E )- and ( Z )-oximes and oxime ethers and subsequent oxazaborolidine-catalyzed enantioselective reduction using different amino alcohols furnished both enantiomers of the important chiral building block 2,2,2-trifluoro-1-furan-2-yl-ethylamine with e.e. of up to 88%. Oxidation of the furan ring afforded both enantiomers of 3,3,3-trifluoroalanine in 91–93% yields." @default.
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- W2000464294 date "2001-09-01" @default.
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- W2000464294 title "An asymmetric synthesis of both enantiomers of 2,2,2-trifluoro-1-furan-2-yl-ethylamine and 3,3,3-trifluoroalanine from 2,2,2-trifluoro-1-furan-2-yl-ethanone" @default.
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- W2000464294 doi "https://doi.org/10.1016/s0957-4166(01)00410-4" @default.
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