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- W2000465752 abstract "Abstract The homo-dinuclear title complexes were prepared and characterized employing analytical and spectral techniques. The ligand binds the metal ions as a bidentate dianionic (dea 2− ) chelating moiety forming M O M bridges to result in homo-dinuclear complexes. The electronic (ligand field) spectral data suggest a hexa-coordinate environment around high spin state of metal ion. EPR data of Cu(II) complexes confirm a distorted octahedral geometry. The observed quadrupole splitting and the relevant parameters δ , Δ E Q and the line width in the 57 Fe Mossbauer spectrum of the iron complex are consistent with a high spin state of Fe(III) in a distorted octahedral environment and the presence of Kramer’s double degeneracy. The CV data suggest probable formation of quasi reversible redox couples Cu II/I or Fe III/II in aqueous solutions of the respective complexes." @default.
- W2000465752 created "2016-06-24" @default.
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- W2000465752 date "2013-03-01" @default.
- W2000465752 modified "2023-09-24" @default.
- W2000465752 title "Synthesis and characterization of homo-dinuclear complexes [M2(dea)2(H2O)4], [M2(dea)2(Bipy)2] and [Fe2(dea)2(H2O)2(Cl)2] (M=Co, Ni or Cu; H2dea=diethanolamine): 57Fe Mössbauer and electrochemical investigations" @default.
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- W2000465752 doi "https://doi.org/10.1016/j.molstruc.2012.11.031" @default.
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