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- W2000469435 abstract "In situ environmental transmission electron microscopy is employed to study the effect of Au composition in Cu-Au alloys on the orientations of oxide islands during the initial-stage oxidation of Cu-Au(100) alloys. An orientation transition from nucleating epitaxial Cu2O islands to randomly oriented oxide islands is observed upon increasing the oxygen gas pressure. By increasing the Au composition in the Cu-Au alloys, both the oxide nucleation time and saturation density of oxide islands increase, but the critical oxygen pressure leading to nucleating randomly oriented Cu2O islands decreases. It is shown by a kinetic model that such a dependence of the critical oxygen pressure on the alloy composition is related to its effect on two competing processes, the oxide-alloy structure match and the effective collision of oxygen atoms, in determining the overall nucleation rate of oxide islands during the oxidation." @default.
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- W2000469435 date "2012-04-15" @default.
- W2000469435 modified "2023-10-18" @default.
- W2000469435 title "Effect of gold composition on the orientations of oxide nuclei during the early stage oxidation of Cu-Au alloys" @default.
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- W2000469435 doi "https://doi.org/10.1063/1.4707929" @default.
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