FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000471846> ?p ?o ?g. }

• W2000471846 abstract "Planar [Ni(bedtc)(PPh3)Cl] (1), [Ni(bedtc)(PPh3)(NCO)] (2), [Ni(bedtc)(PPh3)(NCS)] (3), [Ni(bedtc)(PPh3)(CN)] (4) and [Ni(bedtc)(dppe)]ClO4 (5) (where bedtc = N-benzyl-N-(2-hydroxyethyl)dithiocarbamate anion, PPh3 = triphenylphosphine and dppe = 1,2-bis((diphenylphosphino)ethane)) were prepared from [Ni(bedtc)2]. Complexes 1–5 were characterized by elemental analysis, electronic, IR and NMR (1H, 13C, and 31P) spectra. Electronic spectra of the complexes show bands corresponding to dz 2 → dxy/dx 2 − y 2 transitions. The complexes were diamagnetic. IR and 13C NMR studies indicate the mesomeric flow of π-electron density from the dithiocarbamate towards the nickel. In 1H NMR, α-CH2–and β-CH2–protons of–CH2–CH2–OH were equally deshielded. The deshielding for the coordinated phosphorus signals in 31P NMR spectra for all the cases compared with the free phosphine clearly manifests the drift of electron density from the phosphorus toward the metal on complexation. Single crystal X-ray structures of 1–3 indicate ..." @default.
• W2000471846 created "2016-06-24" @default.
• W2000471846 creator A5030336374 @default.
• W2000471846 creator A5043623254 @default.
• W2000471846 creator A5044635934 @default.
• W2000471846 creator A5053367276 @default.
• W2000471846 creator A5054196470 @default.
• W2000471846 creator A5085522770 @default.
• W2000471846 date "2009-04-10" @default.
• W2000471846 modified "2023-09-24" @default.
• W2000471846 title "Trans influences of Cl−, NCO− and NCS− donors on planar NiS2PN(CO), NiS2PN(CS), NiS2PCl and NiS2P2 chromophores: synthesis, NMR spectral and single crystal X-ray structural studies" @default.
• W2000471846 cites W1965057277 @default.
• W2000471846 cites W1989751879 @default.
• W2000471846 cites W2002907541 @default.
• W2000471846 cites W2021634139 @default.
• W2000471846 cites W2025741446 @default.
• W2000471846 cites W2050576725 @default.
• W2000471846 cites W2059401704 @default.
• W2000471846 cites W2064734407 @default.
• W2000471846 cites W2068359045 @default.
• W2000471846 cites W2070440755 @default.
• W2000471846 cites W2072863162 @default.
• W2000471846 cites W2073233200 @default.
• W2000471846 cites W2100650588 @default.
• W2000471846 cites W2101748147 @default.
• W2000471846 cites W2148066840 @default.
• W2000471846 cites W2318218071 @default.
• W2000471846 cites W2327222076 @default.
• W2000471846 cites W2338341614 @default.
• W2000471846 cites W2949728681 @default.
• W2000471846 cites W2951158181 @default.
• W2000471846 doi "https://doi.org/10.1080/00958970802483624" @default.
• W2000471846 hasPublicationYear "2009" @default.
• W2000471846 type Work @default.
• W2000471846 sameAs 2000471846 @default.
• W2000471846 citedByCount "7" @default.
• W2000471846 countsByYear W20004718462012 @default.
• W2000471846 countsByYear W20004718462014 @default.
• W2000471846 countsByYear W20004718462015 @default.
• W2000471846 countsByYear W20004718462016 @default.
• W2000471846 countsByYear W20004718462020 @default.
• W2000471846 crossrefType "journal-article" @default.
• W2000471846 hasAuthorship W2000471846A5030336374 @default.
• W2000471846 hasAuthorship W2000471846A5043623254 @default.
• W2000471846 hasAuthorship W2000471846A5044635934 @default.
• W2000471846 hasAuthorship W2000471846A5053367276 @default.
• W2000471846 hasAuthorship W2000471846A5054196470 @default.
• W2000471846 hasAuthorship W2000471846A5085522770 @default.
• W2000471846 hasConcept C103319777 @default.
• W2000471846 hasConcept C115624301 @default.
• W2000471846 hasConcept C121332964 @default.
• W2000471846 hasConcept C1276947 @default.
• W2000471846 hasConcept C161790260 @default.
• W2000471846 hasConcept C163111631 @default.
• W2000471846 hasConcept C178790620 @default.
• W2000471846 hasConcept C185592680 @default.
• W2000471846 hasConcept C2777247709 @default.
• W2000471846 hasConcept C2777545050 @default.
• W2000471846 hasConcept C2777716191 @default.
• W2000471846 hasConcept C4839761 @default.
• W2000471846 hasConcept C55493867 @default.
• W2000471846 hasConcept C67787023 @default.
• W2000471846 hasConcept C71240020 @default.
• W2000471846 hasConcept C73922627 @default.
• W2000471846 hasConcept C8010536 @default.
• W2000471846 hasConceptScore W2000471846C103319777 @default.
• W2000471846 hasConceptScore W2000471846C115624301 @default.
• W2000471846 hasConceptScore W2000471846C121332964 @default.
• W2000471846 hasConceptScore W2000471846C1276947 @default.
• W2000471846 hasConceptScore W2000471846C161790260 @default.
• W2000471846 hasConceptScore W2000471846C163111631 @default.
• W2000471846 hasConceptScore W2000471846C178790620 @default.
• W2000471846 hasConceptScore W2000471846C185592680 @default.
• W2000471846 hasConceptScore W2000471846C2777247709 @default.
• W2000471846 hasConceptScore W2000471846C2777545050 @default.
• W2000471846 hasConceptScore W2000471846C2777716191 @default.
• W2000471846 hasConceptScore W2000471846C4839761 @default.
• W2000471846 hasConceptScore W2000471846C55493867 @default.
• W2000471846 hasConceptScore W2000471846C67787023 @default.
• W2000471846 hasConceptScore W2000471846C71240020 @default.
• W2000471846 hasConceptScore W2000471846C73922627 @default.
• W2000471846 hasConceptScore W2000471846C8010536 @default.
• W2000471846 hasLocation W20004718461 @default.
• W2000471846 hasOpenAccess W2000471846 @default.
• W2000471846 hasPrimaryLocation W20004718461 @default.
• W2000471846 hasRelatedWork W1521020042 @default.
• W2000471846 hasRelatedWork W1980222059 @default.
• W2000471846 hasRelatedWork W1980393008 @default.
• W2000471846 hasRelatedWork W1996488673 @default.
• W2000471846 hasRelatedWork W2007699328 @default.
• W2000471846 hasRelatedWork W2012257751 @default.
• W2000471846 hasRelatedWork W2015212728 @default.
• W2000471846 hasRelatedWork W2020053711 @default.
• W2000471846 hasRelatedWork W2025907807 @default.
• W2000471846 hasRelatedWork W2031281677 @default.
• W2000471846 hasRelatedWork W2036260939 @default.
• W2000471846 hasRelatedWork W2036732439 @default.
• W2000471846 hasRelatedWork W2050256031 @default.
• W2000471846 hasRelatedWork W2052906545 @default.
• W2000471846 hasRelatedWork W2055987915 @default.

• next