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• W2000472536 abstract "Abstract A diglycosyl diether was isolated from Methanobacterium thermoautotrophicum (ATCC 29183) which contained one tightly bound Na+ or K+ per molecule of lipid. This compound was part of a family of glycolipids containing tightly bound Na+ or K+. The complex was dissociated with 1 N acid, which changed the Chromatographic properties and the mass spectrum, but not the 1H- and 13C-NMR of the lipid. The Na+ was partially replaced by repeated washing with NaCl. The glycolipids were labelled when the cells were grown in the presence of 22NaCl. Neither 1H- nor 13C-NMR spectra provided any evidence to indicate where the Na+ might be attached. The glycolipid-metal complex appears to add stability to these lipids. It is speculated that these complexes might be involved in the active transport of Na+ and K+ across membranes in extremely thermophilic bacteria. The same diglycosyl diether (2,3- di -O- phytanyl -1-O-[β- d - glucopyranos - yl -(1 → 6)-β- d - glucopyranosyl ]-sn- glycerol ) , without the Na+ or K+, has been described recently in two other methanogens." @default.
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• W2000472536 date "1988-08-01" @default.
• W2000472536 modified "2023-10-02" @default.
• W2000472536 title "The presence of tightly bound Na+ or K+ in glycolipids of Methanobacterium thermoautotrophicum" @default.
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• W2000472536 doi "https://doi.org/10.1016/0005-2760(88)90075-6" @default.
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